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Author(s):   Arican, M.H.; Potter, E.; Whytock, D.A.
Title:   Reactions of trifluoromethyl radicals with propane, n-butane and isobutane
Journal:   J. Chem. Soc. Faraday Trans. 1
Volume:   69
Year:   1973
Reference type:   Journal article
Squib:   1973ARI/POT1811

Reaction:   iso-C4H10 + ·CF3CHF3 + tert-C4H9
Reaction order:   2
Reference reaction:   iso-C4H10 + ·CF3CHF3 + iso-C4H9
Reference reaction order:   2
Temperature:   315 - 405 K
Pressure:  3.71E-2 - 7.20E-2 bar
Rate expression:   4.0x10-2 e18375 [±550 J/mole]/RT
Uncertainty:   1.20000005
Bath gas:   CF3I
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
315 4.46E1
325 3.59E1
350 2.21E1
375 1.45E1
400 1.00E1
405 9.37E0