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Author(s):   Cuevas, C.A.; Notario, A.; Martinez, E.; Albaladejo, J.
Title:   Influence of temperature in the kinetics of the gas-phase reactions of a series of acetates with Cl atoms
Journal:   Atmos. Environ.
Volume:   39
Page(s):   5091 - 5099
Year:   2005
Reference type:   Journal article
Squib:   2005CUE/NOT5091-5099

Reaction:   CH3COO(CH2)3CH3 + ·Cl → Products
Reaction order:   2
Temperature:   265 - 383 K
Pressure:  2.67E-2 - 0.27 bar
Rate expression:   5.41x10-11 [±1.51x10-11 cm3/molecule s] e2037 [±1397 J/mole]/RT
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   Rate constant is pressure independent
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Resonance fluorescence
Comments:   XeCl photolysis of Cl2 employed to generate Cl atoms.

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Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
265 1.36E-10
275 1.32E-10
300 1.22E-10
325 1.15E-10
350 1.09E-10
375 1.04E-10
383 1.03E-10