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Author(s):   Xing, J.H.; Takahashi, K.; Hurley, M.D.; Wallington, T.J.
Title:   Kinetics of the reactions of chlorine atoms with a series of acetates
Journal:   Chem. Phys. Lett.
Volume:   474
Page(s):   268 - 272
Year:   2009
Reference type:   Journal article
Squib:   2009XIN/TAK268-272

Reaction:   CH3COO(CH2)3CH3 + ·Cl → Products
Reaction order:   2
Temperature:   296 K
Pressure:  0.93 bar
Rate expression:   1.37x10-10 [±1.8x10-11 cm3/molecule s]
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   Fourier transform (FTIR)
Comments:   Acetylene and ethylene were used as reference compounds. Quoted rate constant value is an average of the two determinations with uncertainty which encompasses the extremes of the individual determinations.

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