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Author(s):   Xing, J.H.; Takahashi, K.; Hurley, M.D.; Wallington, T.J.
Title:   Kinetics of the reactions of chlorine atoms with a series of acetates
Journal:   Chem. Phys. Lett.
Volume:   474
Page(s):   268 - 272
Year:   2009
Reference type:   Journal article
Squib:   2009XIN/TAK268-272

Reaction:   CH3COO(CH2)3CH3 + ·Cl → Products
Reaction order:   2
Temperature:   295 K
Pressure:  2.53E-3 - 8.80E-3 bar
Rate expression:   1.58x10-10 [±9.4x10-12 cm3/molecule s]
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Laser induced fluorescence
Comments:   Quoted uncertainty includes two standard deviations from the least-squares fit analysis and systematic uncertainty associated with the reactant concentration.

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