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Author(s):   Ifang, S.; Benter, T.; Barnes, I.
Title:   Reactions of Cl atoms with alkyl esters: kinetic, mechanism and atmospheric implications
Journal:   Environ. Sci. Pollut. Res.
Volume:   22
Page(s):   4820 - 4832
Year:   2015
Book Title:   ''
Editor:   ''
Publisher:   ''
Publisher address:   ''
Comments:   ''
Reference type:   Journal article
Squib:   2015IFA/BEN4820-4832

Reaction:   CH3COO(CH2)3CH3 + ·Cl → Products
Reaction order:   2
Reference reaction:   C2H4 + ·Cl → Products
Temperature:   298 K
Pressure:  1.01 bar
Rate expression:   1.2x10-10 [±1.62x10-11 cm3/molecule s]
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   Gas chromatography
Comments:   The quoted errors for the rate coefficients are the 2σ errors from the linear regression analyses of the data plots plus an additional 10 % to account for the uncertainty in the reference compound rate coefficient.

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