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Accessibility information
Author(s):   Knox, J.H.; Nelson, R.L.
Title:   Competitive chlorination reactions in the gas phase: hydrogen and C1-C5 saturated hydrocarbons
Journal:   Trans. Faraday Soc.
Volume:   55
Page(s):  
Year:   1959
Reference type:   Journal article
Squib:   1959KNO/NEL937

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1959KNO/NEL937   CH4 + ·Cl·CH3 + HCl  193 - 593   3.99E-11       1.61E04   5.93E-14  2
  1959KNO/NEL937   CH4 + ·Cl·CH3 + HCl  193 - 593   0.30       -6901   4.86  2
  Reference reaction:  H2 + ·ClHCl + 2
  1959KNO/NEL937   C2H6 + ·Cl·C2H5 + HCl  193 - 593   1.49E-10       4348   2.58E-11  2
  1959KNO/NEL937   C2H6 + ·Cl·C2H5 + HCl  193 - 593   3.85       -1.17E04   437  2
  Reference reaction:  CH4 + ·Cl·CH3 + HCl 2
  1959KNO/NEL937   C3H8 + ·Cliso-C3H7 + HCl  193 - 593   1.19E-10       2844   3.79E-11  2
  1959KNO/NEL937   C3H8 + ·Cliso-C3H7 + HCl  193 - 593   0.78       -1505   1.43  2
  Reference reaction:  C2H6 + ·Cl·C2H5 + HCl 2
  1959KNO/NEL937   C3H8 + ·Cl1-C3H7 + HCl  193 - 593   1.69E-10       4182   3.13E-11  2
  1959KNO/NEL937   C3H8 + ·Cl1-C3H7 + HCl  193 - 593   1.11       -166   1.19  2
  Reference reaction:  C2H6 + ·Cl·C2H5 + HCl 2
  1959KNO/NEL937   Cyclopropane + ·ClCyclopropyl + HCl  193 - 593   8.97E-11       1.73E04   8.34E-14  2
  1959KNO/NEL937   Cyclopropane + ·ClCyclopropyl + HCl  193 - 593   0.56       1.30E04   2.98E-03  2
  Reference reaction:  C2H6 + ·Cl·C2H5 + HCl 2
  1959KNO/NEL937   iso-C4H10 + ·Cltert-C4H9 + HCl  193 - 593   2.82E-11       83.14   2.73E-11  2
  1959KNO/NEL937   iso-C4H10 + ·Cltert-C4H9 + HCl  193 - 593   0.18       -4265   1.01  2
  Reference reaction:  C2H6 + ·Cl·C2H5 + HCl 2
  1959KNO/NEL937   iso-C4H10 + ·Cliso-C4H9 + HCl  193 - 593   1.94E-10       3434   4.86E-11  2
  1959KNO/NEL937   iso-C4H10 + ·Cliso-C4H9 + HCl  193 - 593   1.30       -923   1.89  2
  Reference reaction:  C2H6 + ·Cl·C2H5 + HCl 2
  1959KNO/NEL937   1-C4H10 + ·Clsec-C4H9 + HCl  193 - 593   7.31E-11       1131   4.63E-11  2
  1959KNO/NEL937   1-C4H10 + ·Clsec-C4H9 + HCl  193 - 593   0.94       3218   0.26  2
  Reference reaction:  C2H6 + ·Cl·C2H5 + HCl 2
  1959KNO/NEL937   1-C4H10 + ·Cl1-C4H9 + HCl  193 - 593   1.39E-10       3309   3.66E-11  2
  1959KNO/NEL937   1-C4H10 + ·Cl1-C4H9 + HCl  193 - 593   0.89       -1048   1.36  2
  Reference reaction:  C2H6 + ·Cl·C2H5 + HCl 2
  1959KNO/NEL937   Cyclobutane + ·ClCyclobutyl + HCl  193 - 593   4.25E-10       3451   1.06E-10  2
  1959KNO/NEL937   Cyclobutane + ·ClCyclobutyl + HCl  193 - 593   2.54       732   1.89  2
  Reference reaction:  C3H8 + ·Cl1-C3H7 + HCl 2
  1959KNO/NEL937   neo-C5H12 + ·ClNeopentyl + HCl  193 - 593   2.79E-10       3850   5.90E-11  2
  1959KNO/NEL937   neo-C5H12 + ·ClNeopentyl + HCl  193 - 593   1.65       -333   1.89  2
  Reference reaction:  C3H8 + ·Cl1-C3H7 + HCl 2

Search returned 22 records.