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Author(s):   Park, J.; Burova, S.; Rodgers, A.S.; Lin, M.C.
Title:   Experimental and Theoretical Studies of the C6H5 + C6H6 Reaction
Journal:   J. Phys. Chem. A
Volume:   103
Page(s):   9036 - 9041
Year:   1999
Reference type:   Journal article
Squib:   1999PAR/BUR9036-9041

Reaction:   Benzene + PhenylAcenaphthene +
Reaction order:   2
Temperature:   298 - 1330 K
Pressure:  5.33E-2 bar
Rate expression:   1.59x10-34 [±1.78x10-24 cm3/molecule s] e-18026 [±283 J/mole]/RT
Category:  Review
Data type:   Experimental value and limited review
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Vis-UV absorption
Comments:   THe rate constant was calculated by RRKM theory.

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
298 1.10E-37
300 1.15E-37
400 7.02E-37
500 2.08E-36
600 4.28E-36
700 7.16E-36
800 1.06E-35
900 1.43E-35
1000 1.81E-35
1100 2.21E-35
1200 2.60E-35
1300 2.99E-35
1330 3.11E-35