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Author(s):   Boddy, P.J.; Steacie, E.W.R.
Title:   Hydrogen atom abstraction by ethyl-d5 radicals. Part I
Journal:   Can. J. Chem.
Volume:   38
Page(s):   1576 - 1589
Year:   1960
Reference type:   Journal article
Squib:   1960BOD/STE1576-1589

Reaction:   neo-C5H12 + ·C2D5 → C2HD5 + Neopentyl
Reaction order:   2
Reference reaction:   CD3CD2C(O)CD2CD3 + ·C2D5 → Other Products + C2D6
Reference reaction order:   2
Temperature:   323 - 573 K
Pressure:  6.13E-2 - 0.31 bar
Rate expression:   2.0 e-15049 [±906 J/mole]/RT
Uncertainty:   1.23000002
Bath gas:   neo-C5H12
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Vis-UV absorption

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
323 7.37E-3
325 7.63E-3
350 1.14E-2
375 1.60E-2
400 2.17E-2
425 2.83E-2
450 3.58E-2
475 4.43E-2
500 5.36E-2
525 6.36E-2
550 7.44E-2
573 8.50E-2