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Author(s):   Goulay, F.; Trevitt, A.J.; Meloni, G.; Selby, T.M.; Osborn, D.L.; Taatjes, C.A.; Vereecken, L.; Leone, S.R.
Title:   Cyclic Versus Linear Isomers Produced by Reaction of the Methylidyne Radical (CH) with Small Unsaturated Hydrocarbons
Journal:   J. Am. Chem. Soc.
Volume:   131
Page(s):   993 - 1005
Year:   2009
Reference type:   Journal article
Squib:   2009GOU/TRE993-1005

Reaction:   C2H4 + ·CHCH3CCH +
Reaction order:   2
Reference reaction:   C2H4 + ·CH → Products
Reference reaction order:   2
Temperature:   298 K
Pressure:  2.67E-3 - 8.00E-3 bar
Rate expression:   3.0x10-1±8.0x10-2
Category:  Experiment
Data type:   Relative rate value measured
Pressure dependence:   Rate constant is pressure independent
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Mass spectrometry
Comments:   Error bars are reported as 2σ.

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