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Author(s):   Dean, A.M.
Title:   Predictions of pressure and temperature effects upon radical addition and recombination reactions
Journal:   J. Phys. Chem.
Volume:   89
Page(s):   4600 - 4608
Year:   1985
Reference type:   Journal article
Squib:   1985DEA4600-4608

Reaction:   1,2-butadiene + 2,3-Butanediyl
Reaction order:   1
Temperature:   300 - 2500 K
Rate expression:   2.0x1015 [s-1] e-359185 [J/mole]/RT
Category:  Experiment
Data type:   RRK(M) extrapolation

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
300 5.79E-48
400 2.50E-32
500 6.00E-23
600 1.08E-16
700 3.15E-12
800 7.07E-9
900 2.85E-6
1000 3.46E-4
1100 1.76E-2
1200 4.64E-1
1300 7.40E0
1400 7.94E1
1500 6.21E2
1600 3.76E3
1700 1.84E4
1800 7.55E4
1900 2.67E5
2000 8.32E5
2100 2.33E6
2200 5.93E6
2300 1.39E7
2400 3.05E7
2500 6.26E7