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Author(s):   Kennedy, R.C.; Levy, J.B.
Title:   Bistrifluoromethyl peroxide. II. Kinetics of the decomposition to carbonyl fluoride and trifluoromethyl hypofluorite
Journal:   J. Phys. Chem.
Volume:   76
Page(s):   3480 - 3488
Year:   1972
Reference type:   Journal article
Squib:   1972KEN/LEV3480-3488

Reaction:   COF2 + ·FCF3O
Reaction order:   2
Reference reaction:   CF3OCOF2 + ·F
Temperature:   484 - 577 K
Pressure:  5.33E-3 - 1.15 bar
Rate expression:   4.17x10-12 [cm3/molecule s] e-33923 [±8314472 J/mole]/RT
Uncertainty:   1.58000004
Bath gas:   CF3O-OCF3
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Pressure measurement

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
484 9.10E-16
500 1.19E-15
525 1.76E-15
550 2.50E-15
575 3.45E-15
577 3.54E-15