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Author(s):   Robichaud, D. J.; Scheer, A. M.; Mukarakate, C.; Ormond, T. K.; Buckingham, G. T.; Ellison, G. B.; Nimlos, M. R.
Title:   Unimolecular thermal decomposition of dimethoxybenzenes
Journal:   J. Chem. Phys.
Volume:   140
Year:   2014
Reference type:   Journal article
Squib:   2014ROB/SCH234302

Reaction:   1,4-Dimethoxybenzene → Products
Reaction order:   1
Temperature:   400 - 1600 K
Rate expression:   no rate data available
Category:  Experiment
Data type:   Mechanistic information only
Pressure dependence:   None reported
Experimental procedure:   Other
Excitation technique:   Thermal
Time resolution:   By end product analysis
Analytical technique:   Mass spectrometry
Comments:   The unimolecular thermal decomposition mechanism of the reactant was studied using a high temperature, microtubular SiC reactor with a residence time of 100 μs. Product detection was carried out using single photon ionization and resonance enhanced multiphoton ionization time-of-flight mass spectrometry and matrix infrared absorption spectroscopy. Product channels of subsequent reactions were analyzed.

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