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Title: Gas-phase Unimolecular Pyrolyses of cis- and trans-2,3-Dimethyloxetan
Journal: J. Chem. Soc. Faraday Trans. 1
Volume: 70
Page(s):
Year: 1974
Reference type: Journal article
Squib: 1974HOL/SCO43
Reaction:
cis-2,3-dimethyl-oxetane → CH2O + CH3CH=CHCH3
Reaction order:
1
Temperature:
688 - 756
K
Pressure: 2.67E-3 - 4.27E-2 bar
Rate expression:
1.74x1015 [s-1] e-261074 [±2611 J/mole]/RT
Uncertainty:
1.77999997
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 688 | 2.63E-5 |
| 700 | 5.75E-5 |
| 725 | 2.70E-4 |
| 750 | 1.14E-3 |
| 756 | 1.59E-3 |