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Accessibility information
Author(s):   Vijayakumar, S.; Kumar, A.; Rajakumar, B.
Title:   Experimental and computational kinetic investigations for the reactions of Cl atoms with unsaturated ketones in the gas phase
Journal:   New J. Chem.
Volume:   41
Page(s):   14299 - 14314
Year:   2017
Reference type:   Journal article
Squib:   2017VIJ/KUM14299-14314

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2017VIJ/KUM14299-14314   (E)-CH3CH=CHC(=O)C2H5 + ·Cl → Products  298 - 363   2.82E-12       -1.29E04   5.22E-10  2
  2017VIJ/KUM14299-14314   5-Hexen-2-one + ·Cl → Products  298 - 363   4.60E-11       -5371   4.02E-10  2
  2017VIJ/KUM14299-14314   5-Hexen-2-one + ·Cl → Products  275 - 400   3.20E-12       -1.28E04   5.52E-10  2
  2017VIJ/KUM14299-14314   (E)-CH3CH=CHC(=O)C2H5 + ·Cl → Products  275 - 400   1.41E-12       -1.38E04   3.74E-10  2
  2017VIJ/KUM14299-14314   (E)-CH3C(O)CH=CHCH3 + ·Cl → Products  275 - 400   2.50E-12       -1.13E04   2.42E-10  2

Search returned 5 records.