Kinetics Database Logo     Home
©NIST, 2022
Accessibility information
Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Contact Us to Submit an Article

Citation

Help


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...


Administrative Links

DOC home page

NIST home page

MML home page

Chemical Sciences Division

Applied Chemicals and Materials Division

Author(s):   Kunz, A.; Roth, P.
Title:   High-Temperature Kinetics of Some Si- and Cl-Containing Ceramic Precursors
Journal:   Int J. Chem. Kinet.
Volume:   33
Page(s):   741 - 754
Year:   2001
Reference type:   Journal article
Squib:   2001KUN/ROT741-754

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2001KUN/ROT741-754   SiCl4SiCl3 + ·Cl  1500 - 2400   1.15E-07       3.14E05      2
  2001KUN/ROT741-754   SiClSi + ·Cl  2300 - 3700   0.11   -7.00   4.10E05      2
  2001KUN/ROT741-754   SiCl3SiCl2 + ·Cl  1500 - 3700   7.64E-09       2.73E05      2
  2001KUN/ROT741-754   SiCl2SiCl + ·Cl  1500 - 3700   2.82E-09       3.07E05      2
  2001KUN/ROT741-754   SiCl4SiCl3 + ·Cl  1700 - 3300   8.97E-09       3.27E05      2
  2001KUN/ROT741-754   SiCl4 + ·ClCl2 + SiCl3  1000 - 2040   <1.66E-14              2
  2001KUN/ROT741-754   Si + HCl + SiCl  1500 - 2900   1.58E-09       5.70E04      2
  2001KUN/ROT741-754   CH4 + SiH2 + SiCH2  1500 - 2600   <1.66E-12              2
  2001KUN/ROT741-754   ·CH3 + Si → SiCH + H2  1500 - 2600   3.64E-10              2
  2001KUN/ROT741-754   Si + ·CH2SiC + H2  1500 - 2600   3.32E-10              2

Search returned 10 records.