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Title: The reactions of alkyl radicals. Part VI. The reactions of methyl radicals with aliphatic aldehydes
Journal: J. Chem. Soc.
Page(s):
Year: 1960
Reference type: Journal article
Squib: 1960BIR/TRO2059
Reaction:
CH3CH2CH2CHO + ·CH3 → CH4 + CH3CH2CH2CO
Reaction order:
2
Reference reaction:
·CH3 + ·CH3 → C2H6
Temperature:
394 - 447
K
Pressure: 6.19E-2 - 7.08E-2 bar
Rate expression:
1.05x10-12 [cm3/molecule s] e-30514 [±1222 J/mole]/RT
Uncertainty:
1.58000004
Bath gas:
(tert-C4H9O)2
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 394 | 9.44E-17 |
| 400 | 1.09E-16 |
| 425 | 1.86E-16 |
| 447 | 2.85E-16 |