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Accessibility information
Author(s):   Tsang, W.
Title:   Thermal decomposition of some alkyl halides by a shock-tube method
Journal:   J. Chem. Phys.
Volume:   41
Page(s):   2487 - 2494
Year:   1964
Reference type:   Journal article
Squib:   1964TSA2487-2494

Reaction:   tert-C4H9Iiso-C4H8 + HI
Reaction order:   1
Reference reaction:   iso-C3H7BrCH3CH=CH2 + HBr
Temperature:   650 - 760 K
Pressure:  0.60 - 2.00 bar
Rate expression:   5.37x1013 [s-1] e-159638 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
650 7.97E0
675 2.38E1
700 6.58E1
725 1.69E2
750 4.09E2
760 5.73E2