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Accessibility information
Author(s):   Hippler, H.; Riedl, A.; Troe, J.; Willner, J.
Title:   Thermal decomposition of t-butyl bromide and t-butyl iodide in shock waves
Journal:   Z. Phys. Chem. (Neue Folge)
Volume:   171
Page(s):   161 - 177
Year:   1991
Reference type:   Journal article
Squib:   1991HIP/RIE161-177

Reaction:   tert-C4H9Iiso-C4H8 + HI
Reaction order:   1
Temperature:   466 - 1020 K
Pressure:  1.40 - 176 bar
Rate expression:   7.94x1013 [s-1] e-163795 [±3284 J/mole]/RT
Bath gas:   Ar
Category:  Review
Data type:   Experimental value and limited review

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
466 3.47E-5
500 6.15E-4
550 2.21E-2
600 4.37E-1
650 5.46E0
700 4.76E1
750 3.11E2
800 1.60E3
850 6.83E3
900 2.48E4
950 7.83E4
1000 2.21E5
1020 3.25E5