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Accessibility information
Author(s):   Senosiain, J.P.; Miller, J.A.
Title:   The reaction of n- and i-C4H5 radicals with acetylene
Journal:   J. Phys. Chem. A
Volume:   111
Page(s):   3740 - 3747
Year:   2007
Reference type:   Journal article
Squib:   2007SEN/MIL3740-3747

Reaction:   C2H2 + CH2CHC·CH2Benzene +
Reaction order:   2
Temperature:   800 - 2500 K
Rate expression:   1.37x10-9 [cm3/molecule s] (T/298 K)-3.21 e-103075 [J/mole]/RT
Category:  Theory
Data type:   Transition state theory
Pressure dependence:   Rate constant is low pressure limit

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
800 1.07E-17
900 4.11E-17
1000 1.16E-16
1100 2.64E-16
1200 5.11E-16
1300 8.75E-16
1400 1.36E-15
1500 1.97E-15
1600 2.69E-15
1700 3.49E-15
1800 4.35E-15
1900 5.26E-15
2000 6.18E-15
2100 7.10E-15
2200 7.99E-15
2300 8.85E-15
2400 9.67E-15
2500 1.04E-14