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Accessibility information
Author(s):   Williams, R.J.
Title:   The mechanisms of the thermal decompositions of 1:4-dichlorobutane and 1:1:2-trichloroethane
Journal:   J. Chem. Soc.
Page(s):   113 - 116
Year:   1953
Reference type:   Journal article
Squib:   1953WIL113-116

Reaction:   CH2ClCH2CH2CH2Cl1,3-Butadiene + HCl + HCl
Reaction order:   1
Temperature:   673 - 727 K
Pressure:  5.33E-2 bar
Rate expression:   2.29x1014 [s-1] e-236131 [J/mole]/RT
Bath gas:   CH2ClCH2CH2CH2Cl
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Other (direct)

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
673 1.08E-4
675 1.22E-4
700 5.49E-4
725 2.23E-3
727 2.48E-3