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Title: Rate Constant Measurements at Constant Temperature by the Flash Photolysis-Resonance Fluorescence Technique and Recombination-Dissociation Theory for NO2 and NOCl
Journal: J. Phys. Chem.
Volume: 83
Page(s):
Year: 1979
Reference type: Journal article
Squib: 1979MIC/LEE10
Reaction:
NO + ·Cl → NOCl
Reaction order:
3
Temperature:
200 - 400
K
Pressure: 1.33E-2 - 0.16 bar
Rate expression:
1.18x10-32 [cm6/molecule2 s] e4423 [±177 J/mole]/RT
Bath gas:
N2
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Flash photolysis (laser or conventional)
Analytical technique:
Resonance fluorescence
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm6/molecule2 s] |
|---|---|
| 200 | 1.69E-31 |
| 225 | 1.26E-31 |
| 250 | 9.93E-32 |
| 275 | 8.19E-32 |
| 300 | 6.97E-32 |
| 325 | 6.08E-32 |
| 350 | 5.41E-32 |
| 375 | 4.89E-32 |
| 400 | 4.47E-32 |