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Author(s):   Rice, F.O.; Varnerin, R.E.
Title:   Activation energies of reactions of methyl radicals with organic molecules
Journal:   J. Am. Chem. Soc.
Volume:   77
Page(s):  
Year:   1955
Reference type:   Journal article
Squib:   1955RIC/VAR221

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1955RIC/VAR221   Acetone + ·CH3CH4 + CH3C(O)CH2(·)  773 - 833   2.85       1.18E04      2
  Reference reaction:  CD3CDO + CD3CD4 + CD3CO 2
  1955RIC/VAR221   Acetone + ·CH3CH4 + CH3C(O)CH2(·)  823 - 873   1.53       -6901      2
  Reference reaction:  C2D6 + ·CH3CH3D + ·C2D5 2
  1955RIC/VAR221   CH4 + ·CH3CH4 + ·CH3  800   0.08              2
  Reference reaction:  CD3CDO + CD3CD4 + CD3CO 2
  1955RIC/VAR221   C2H6 + ·CH3CH4 + ·C2H5  773 - 833   1.36       1.10E04      2
  Reference reaction:  CD3CDO + CD3CD4 + CD3CO 2
  1955RIC/VAR221   C2H4 + ·CH3CH4 + C2H3  773 - 833   0.10              2
  Reference reaction:  CD3CDO + CD3CD4 + CD3CO 2
  1955RIC/VAR221   C3H8 + ·CH3 → Products  853   5.24              2
  Reference reaction:  C2D6 + ·CH3CH3D + ·C2D5 2
  1955RIC/VAR221   CH3CHO + ·CH3CH4 + CH3CO  773 - 833   0.58       -8564      2
  Reference reaction:  CD3CDO + CD3CD4 + CD3CO 2
  1955RIC/VAR221   CH3CHO + ·CH3CH4 + CH3CO  803 - 843   2.47       -1.76E04      2
  Reference reaction:  C2D6 + ·CH3CH3D + ·C2D5 2
  1955RIC/VAR221   iso-C4H10 + ·CH3 → Other Products + CH4  773 - 833   2.13       7965      2
  Reference reaction:  CD3CDO + CD3CD4 + CD3CO 2
  1955RIC/VAR221   iso-C4H10 + ·CH3 → Other Products + CH4  853   8.09              2
  Reference reaction:  C2D6 + ·CH3CH3D + ·C2D5 2
  1955RIC/VAR221   2,3-Dimethylbutane + ·CH3 → Other Products + CH4  773 - 833   0.87              2
  Reference reaction:  CD3CDO + CD3CD4 + CD3CO 2
  1955RIC/VAR221   1-C4H10 + ·CH3 → Other Products + CH4  773 - 833   4.47       1.26E04      2
  Reference reaction:  CD3CDO + CD3CD4 + CD3CO 2
  1955RIC/VAR221   1-C4H10 + ·CH3 → Other Products + CH4  853   7.29              2
  Reference reaction:  C2D6 + ·CH3CH3D + ·C2D5 2
  1955RIC/VAR221   n-C5H12 + ·CH3 → Other Products + CH4  800   0.84              2
  Reference reaction:  CD3CDO + CD3CD4 + CD3CO 2
  1955RIC/VAR221   n-C5H12 + ·CH3 → Other Products + CH4  813 - 853   5.65       -8980      2
  Reference reaction:  C2D6 + ·CH3CH3D + ·C2D5 2
  1955RIC/VAR221   CH3CH=CH2 + ·CH3CH4 + ·CH2CH=CH2  773 - 833   0.66       2577      2
  Reference reaction:  CD3CDO + CD3CD4 + CD3CO 2
  1955RIC/VAR221   Dimethyl ether + ·CH3CH4 + CH3OCH2·  773 - 833   5.42       1.46E04      2
  Reference reaction:  CD3CDO + CD3CD4 + CD3CO 2
  1955RIC/VAR221   Dimethyl ether + ·CH3CH4 + CH3OCH2·  803 - 853   6.05       -3825      2
  Reference reaction:  C2D6 + ·CH3CH3D + ·C2D5 2
  1955RIC/VAR221   neo-C5H12 + ·CH3CH4 + Neopentyl  773 - 833   3.21       1.52E04      2
  Reference reaction:  CD3CDO + CD3CD4 + CD3CO 2
  1955RIC/VAR221   neo-C5H12 + ·CH3CH4 + Neopentyl  843 - 883   2.02       -5471      2
  Reference reaction:  C2D6 + ·CH3CH3D + ·C2D5 2

Search returned 20 records.