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Title: The kinetics of the forward and reverse reactions for the vapor phase thermal bromination of chloroform
Journal: J. Chem. Phys.
Volume: 19
Page(s): 143 - 148
Year: 1951
Reference type: Journal article
Squib: 1951SUL/DAV143-148
Reaction:
CHCl3 + Br· → ·CCl3 + HBr
Reaction order:
2
Temperature:
420 - 455
K
Rate expression:
3.8x10-12 [cm3/molecule s] e-38912 [±1164 J/mole]/RT
Bath gas:
CHCl3
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Thermal
Analytical technique:
Other (direct)
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 420 | 5.51E-17 |
| 425 | 6.28E-17 |
| 450 | 1.16E-16 |
| 455 | 1.30E-16 |