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Accessibility information
Author(s):   Sullivan, J.H.; Davidson, N.
Title:   The kinetics of the forward and reverse reactions for the vapor phase thermal bromination of chloroform
Journal:   J. Chem. Phys.
Volume:   19
Page(s):   143 - 148
Year:   1951
Reference type:   Journal article
Squib:   1951SUL/DAV143-148

Reaction:   CHCl3 + Br··CCl3 + HBr
Reaction order:   2
Temperature:   420 - 455 K
Rate expression:   3.8x10-12 [cm3/molecule s] e-38912 [±1164 J/mole]/RT
Bath gas:   CHCl3
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Other (direct)

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
420 5.51E-17
425 6.28E-17
450 1.16E-16
455 1.30E-16