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Title: Bromination of fluoroalkanes. Part 4.-Kinetics of thermal bromination of fluoroform and pentafluorethane
Journal: Trans. Faraday Soc.
Volume: 64
Page(s):
Year: 1968
Reference type: Journal article
Squib: 1968AMP/WHI2130
Reaction:
CHCl3 + Br· → ·CCl3 + HBr
Reaction order:
2
Temperature:
420 - 455
K
Rate expression:
3.8x10-12 [cm3/molecule s] e-38912 [±125 J/mole]/RT
Uncertainty:
1.40999997
Bath gas:
CHCl3
Category: Review
Data type:
Experimental value and limited review
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 420 | 5.51E-17 |
| 425 | 6.28E-17 |
| 450 | 1.16E-16 |
| 455 | 1.30E-16 |