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Author(s):   Vaughan, S.;Canosa-Mas, C.E.;Pfrang, C.;Shallcross, D.E.;Watson, L.;Wayne, R.P.
Title:   Kinetic studies of reactions of the nitrate radical (NO3) with peroxy radicals (RO2): an indirect source of OH at night?
Journal:   Phys. Chem. Chem. Phys.
Volume:   8
Page(s):   3749 - 3760
Year:   2006
Reference type:   Journal article
Squib:   2006VAU/CAN3749-3760

Reaction:   NO3 + CF3O2 → Products
Reaction order:   2
Temperature:   295 K
Pressure:  6.67E-3 bar
Rate expression:   6.2x10-13 [±1.7x10-13 cm3/molecule s]
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Pressure dependence:   None reported
Experimental procedure:   Flow tube - Data taken vs distance
Excitation technique:   Discharge
Time resolution:   By end product analysis
Analytical technique:   Vis-UV absorption
Comments:   Errors include contributions suggested by the sensitivity analysis of the kinetic model.

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