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Accessibility information
Author(s):   Dean, A.M.
Title:   Predictions of pressure and temperature effects upon radical addition and recombination reactions
Journal:   J. Phys. Chem.
Volume:   89
Page(s):   4600 - 4608
Year:   1985
Reference type:   Journal article
Squib:   1985DEA4600-4608

Reaction:   CH3CH=CHCH3·CH3 + CH3CH=C(·)H
Reaction order:   1
Temperature:   300 - 2500 K
Rate expression:   3.16x1017 [s-1] e-415724 [J/mole]/RT
Category:  Experiment
Data type:   RRK(M) extrapolation

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
300 1.31E-55
400 1.63E-37
500 1.18E-26
600 2.03E-19
700 3.01E-14
800 2.27E-10
900 2.36E-7
1000 6.09E-5
1100 5.74E-3
1200 2.54E-1
1300 6.25E0
1400 9.75E1
1500 1.05E3
1600 8.47E3
1700 5.33E4
1800 2.73E5
1900 1.18E6
2000 4.39E6
2100 1.44E7
2200 4.26E7
2300 1.14E8
2400 2.83E8
2500 6.51E8