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Title: Kinetics of Reactions of Chlorine Atoms with a Series of Alkenes at 1 atm and 298 K: Structure and Reactivity
Journal: Phys. Chem. Chem. Phys.
Volume: 1
Page(s): 5813 - 5820
Year: 2002
Reference type: Journal article
Squib: 2002EZE/WAN5813-5820
Reaction:
(CH3)2C=CHCH3 + ·Cl → Products
Reaction order:
2
Reference reaction:
1-C7H16 + ·Cl → Products
Temperature:
298
K
Pressure: 1.01 bar
Rate expression:
3.95x10-10 [±3.2x10-11 cm3/molecule s]
Category: Experiment
Data type:
Relative value normalized by a reference value
Pressure dependence:
None reported
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Direct photolysis
Time resolution:
By end product analysis
Analytical technique:
Gas chromatography
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