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 Author(s):   Tranter, R.S.; Klippenstein, S.J.; Harding, L.B.; Giri, B.R.; Yang, X.L.; Kiefer, J.H.
Title:   Experimental and Theoretical Investigation of the Self-Reaction of Phenyl Radicals
Journal:   J. Phys. Chem. A
Volume:   114
Page(s):   8240 - 8261
Year:   2010
Reference type:   Journal article
Squib:   2010TRA/KLI8240-8261

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
    2010TRA/KLI8240-8261   Iodobenzene → Phenyl + I  1246 - 1853                  1
  2010TRA/KLI8240-8261   Iodobenzene → Phenyl + I  1000 - 1900   3.95E16   -0.98   2.85E05      1
  2010TRA/KLI8240-8261   Iodobenzene → o-C6H4 + HI  1276 - 1853   0.06              1
  Reference reaction:  Iodobenzene → Products 1
  2010TRA/KLI8240-8261   Phenyl + Phenyl → Biphenyl  200 - 2500   2.03E-11   -0.45   -2303   5.14E-11  2
  2010TRA/KLI8240-8261   [1,1'-Biphenyl]-2-yl + H· → Biphenyl  200 - 2500   4.86E-10   0.34   -662   6.35E-10  2
  2010TRA/KLI8240-8261   [1,1'-Biphenyl]-3-yl + H· → Biphenyl  200 - 2500   1.05E-10   0.28   -648   1.36E-10  2
  2010TRA/KLI8240-8261   [1,1'-Biphenyl]-4-yl + H· → Biphenyl  200 - 2500   1.32E-10   0.19   64.02   1.29E-10  2
  2010TRA/KLI8240-8261   Phenyl + Phenyl → 3o-C6H4 + Benzene  200 - 2500   5.56E-14   3.07   1.67E04   6.63E-17  2
  2010TRA/KLI8240-8261   Phenyl + Phenyl → 3m-C6H4 + Benzene  200 - 2500   4.58E-14   3.12   1.10E04   5.33E-16  2
  2010TRA/KLI8240-8261   Phenyl + Phenyl → 3p-C6H4 + Benzene  200 - 2500   2.24E-14   3.13   6693   1.50E-15  2
  2010TRA/KLI8240-8261   Phenyl + Phenyl → o-C6H4 + Benzene  200 - 2500   1.07E-14   2.70   -1.84E04   1.82E-11  2
  2010TRA/KLI8240-8261   Phenyl + Phenyl → Benzene + m-Benzyne  200 - 2500   1.21E-14   2.90   -1.17E04   1.34E-12  2
  2010TRA/KLI8240-8261   Phenyl + Phenyl → p-C6H4 + Benzene  200 - 2500   7.22E-15   3.13   4107   1.38E-15  2
  2010TRA/KLI8240-8261   Phenyl + Phenyl → (3)cyc-CHCHCHCHCHC(C6H5)-  300 - 2500   1.40E-14   2.66   -292      2
  2010TRA/KLI8240-8261   Phenyl + Phenyl → (3)cyc-CHCHCHCHCH(C6H5)C-  300 - 2500   1.38E-14   2.97   -9146      2
  2010TRA/KLI8240-8261   Phenyl + Phenyl → (3)cyc-CHCHCHCH(C6H5)CHC-  300 - 2500   1.14E-14   3.04   -7774      2
  2010TRA/KLI8240-8261   Phenyl + Phenyl → cyc-CHCHCHCH(C6H5)CHC-  300 - 2500   4.75E-15   3.05   -8813      2
  2010TRA/KLI8240-8261   Phenyl + Phenyl → (3)cyc-CHCHCH(C6H5)CHCHC-  300 - 2500   9.60E-15   2.53   -8132      2
  2010TRA/KLI8240-8261   Phenyl + Phenyl → cyc-CHCHCH(C6H5)CHCHC-  300 - 2500   2.60E-15   3.18   1139      2
  2010TRA/KLI8240-8261   Phenyl + Phenyl → Biphenyl  1246 - 1853   5.96E-09   -2.81   2.00E04      2
Search returned 20 records.