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Accessibility information
Author(s):   Dijkstra, A.J.; Kerr, J.A.; Trotman-Dickenson, A.F.
Title:   Reactions of difluoroamino-radicals. Part III. Addition to olefins
Journal:   J. Chem. Soc. A
Page(s):  
Year:   1967
Reference type:   Journal article
Squib:   1967DIJ/KER105

Reaction:   CH3CH(NF2)CHCH3(E)-2-C4H8 + NF2
Reaction order:   1
Reference reaction:   NF2 + CH3CH(NF2)CHCH3 → CH3CH(NF2)CH(NF2)CH3
Reference reaction order:   2
Temperature:   334 - 428 K
Rate expression:   2.41x1024 [molecule/cm3] e-56871 [J/mole]/RT
Bath gas:   N2F4
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [molecule/cm3]
334 3.08E15
350 7.84E15
375 2.89E16
400 9.02E16
425 2.47E17
428 2.76E17