Author(s):   Parker, J.K.; Garland, N.L.; Nelson, H.H.
Title:   Kinetics of the Reaction Al + SF₆ in the Temperature Range 499-813 K
Journal:   J. Phys. Chem. A
Volume:   106
Page(s):   307 - 311
Year:   2002
Reference type:   Journal article
Squib:   2002PAR/GAR307-311

Associated entries:

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Rate expression: k(T) = A (T/298 K)ⁿ e^-Ea/RT
Rate expression units:
First order: s^-1
Second order: cm³/molecule s
Third order: cm⁶/molecule² s
R = 8.314472 J / mole K

Energy Units	J	Molecular Units	Molecule
Pressure Units	bar	Temperature Units	K
Base Volume Unit	cm	Reference Temperature	298.0
Evaluation Temperature	298.0

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Squib	Reaction	Temp [K]	A	Ea [J/mole]	Order
2002PAR/GAR307-311	SF₆ + Al → SF₅ + AlF	499 - 813	6.80E-10	3.97E04	2
2002PAR/GAR307-311	Al(CH₃)3 + Al → Al(CH₃)Al(CH₃)2	296	1.30E-10		2
2002PAR/GAR307-311	SF₆ + Al → SF₅ + AlF	500 - 800	2.20E-10	4.52E04	2

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