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Title: Gas phase kinetic and thermochemical data for endo- and exo-5-monosubstituted bicyclo[2.2.2]oct-2-enes
Journal: Int. J. Chem. Kinet.
Volume: 18
Page(s):
Year: 1986
Reference type: Journal article
Squib: 1986VAN/BOO537
Reaction:
bicyclo[2.2.2]oct-2-ene, 5-ethyl-,(1α,4α,5β)- → 1-C4H8 + 1,3-Cyclohexadiene
Reaction order:
1
Temperature:
567 - 670
K
Pressure: 4.00E-3 - 1.07E-2 bar
Rate expression:
1.66x1015 [s-1] e-244445 [J/mole]/RT
Uncertainty:
1.100000023841858
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 567 | 5.02E-8 |
| 575 | 1.03E-7 |
| 600 | 8.70E-7 |
| 625 | 6.18E-6 |
| 650 | 3.77E-5 |
| 670 | 1.46E-4 |