Kinetics Database Logo     Home
©NIST, 2023
Accessibility information
Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Contact Us to Submit an Article



Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

DOC home page

NIST home page

MML home page

Chemical Sciences Division

Applied Chemicals and Materials Division

Author(s):   Boddy, P.J.; Steacie, E.W.R.
Title:   Hydrogen atom abstraction by ethyl-d5 radicals. Part I
Journal:   Can. J. Chem.
Volume:   38
Page(s):   1576 - 1589
Year:   1960
Reference type:   Journal article
Squib:   1960BOD/STE1576-1589

Reaction:   neo-C5H12 + ·C2D5 → C2HD5 + Neopentyl
Reaction order:   2
Reference reaction:   CD3CD2C(O)CD2CD3 + ·C2D5 → Other Products + C2D6
Reference reaction order:   2
Temperature:   323 - 573 K
Pressure:  6.13E-2 - 0.31 bar
Rate expression:   2.0 e-15049 [±906 J/mole]/RT
Uncertainty:   1.2300000190734863
Bath gas:   neo-C5H12
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
323 7.37E-3
325 7.63E-3
350 1.14E-2
375 1.60E-2
400 2.17E-2
425 2.83E-2
450 3.58E-2
475 4.43E-2
500 5.36E-2
525 6.36E-2
550 7.44E-2
573 8.50E-2