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Title: Ultraviolet absorption cross sections and reaction kinetics and mechanisms for peroxy radicals in the gas phase
Journal: Chem. Rev.
Volume: 92
Page(s): 667 - 710
Year: 1992
Reference type: Journal article
Squib: 1992WAL/DAG667-710
Reaction:
CH3O2· + NO2 → CH3O2NO2
Reaction order:
2
Temperature:
253 - 353
K
Rate expression:
8.0x10-12 [cm3/molecule s] (T/298 K)-3.50
Bath gas:
N2
Category: Review
Data type:
Extensive literature review
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 253 | 1.42E-11 |
| 275 | 1.06E-11 |
| 300 | 7.82E-12 |
| 325 | 5.91E-12 |
| 350 | 4.56E-12 |
| 353 | 4.42E-12 |