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Author(s):   Abdel-Rahman, M.A.; Al-Hashimi, N.; Shibl, M.F.; KazunariYoshizawa, ; El-Nahas, A.M.
Title:   Thermochemistry and Kinetics of the Thermal Degradation of 2-Methoxyethanol as Possible Biofuel Additives
Journal:   Sci. Rep
Volume:   9
Year:   2019
Reference type:   Journal article
Squib:   2019ABD/ALH4535

Reaction:   HOCH2CH2OCH3CH2=CHOCH3 + H2O
Reaction order:   1
Temperature:   298 - 2000 K
Rate expression:   4.92x105 [s-1] (T/298 K)8.04 e-218371 [J/mole]/RT
Category:  Theory
Data type:   Transition state theory
Pressure dependence:   Rate constant is high pressure limit
Comments:   Reaction potential energy surface was studied using quantum chemistry and rate constants were calculated using transition state theory.

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
298 2.61E-33
300 4.95E-33
400 1.60E-22
500 4.86E-16
600 1.33E-11
700 2.39E-8
800 7.63E-6
900 7.55E-4
1000 3.26E-2
1100 7.63E-1
1200 1.12E1
1300 1.15E2
1400 8.85E2
1500 5.38E3
1600 2.70E4
1700 1.15E5
1800 4.31E5
1900 1.44E6
2000 4.33E6