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Title: The decomposition of 2-pentyl and 3-pentyl radicals
Journal: Proc. Combust. Inst.
Volume: 34
Page(s): 537 - 545
Year: 2013
Book Title: ''
Editor: ''
Publisher: ''
Publisher address: ''
Comments: ''
Reference type: Journal article
Squib: 2013MAN/AWA537-545
Reaction:
2-(E)-C5H10 + H· → CH3CH2CH2CH(·)CH3
Reaction order:
2
Reference reaction:
1,3,5-Trimethylbenzene + H· → 1,3-Dimethylbenzene + ·CH3
Temperature:
942 - 1075
K
Pressure: 1.20 - 8.00 bar
Rate expression:
7.07x10-11 [cm3/molecule s] e-15407 [J/mole]/RT
Category: Experiment
Data type:
Relative value normalized by a reference value
Pressure dependence:
Rate constant is pressure independent
Experimental procedure:
Shock tube
Excitation technique:
Thermal
Time resolution:
By end product analysis
Analytical technique:
GC-MS
Comments:
Standard uncertainties in the absolute rate constants and activation energies are estimated at about 30% and 5 kJ/mol, respectively.
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 942 | 9.89E-12 |
| 950 | 1.01E-11 |
| 975 | 1.06E-11 |
| 1000 | 1.11E-11 |
| 1025 | 1.16E-11 |
| 1050 | 1.21E-11 |
| 1075 | 1.26E-11 |