NIST Chemical Kinetics Database

Author(s):   Manion, J.A.; Awan, I.A.
Title:   The decomposition of 2-pentyl and 3-pentyl radicals
Journal:   Proc. Combust. Inst.
Volume:   34
Page(s):   537 - 545
Year:   2013
Book Title:   ''
Editor:   ''
Publisher:   ''
Publisher address:   ''
Comments:   ''
Reference type:   Journal article
Squib:   2013MAN/AWA537-545

Reaction:   1-C₅H₁₁ → CH₃CH₂CH₂CH(·)CH₃
Reaction order:   1
Temperature:   400 - 1900 K
Rate expression:   3.67x10⁸ [s^-1] (T/298 K)^3.03 e^{-64071 [J/mole]/RT}
Category: Theory
Data type:   Transition state theory
Pressure dependence:   Rate constant is high pressure limit
Comments:   Rate constants were calculated using transition state theory using potential energy surface properties from the literature.

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)	k(T) [s^-1]
400	3.85E0
500	3.57E2
600	8.10E3
700	8.10E4
800	4.81E5
900	2.00E6
1000	6.49E6
1100	1.75E7
1200	4.08E7
1300	8.52E7
1400	1.63E8
1500	2.90E8
1600	4.86E8
1700	7.75E8
1800	1.19E9
1900	1.75E9