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Accessibility information
Author(s):   Knox, J.H.; Nelson, R.L.
Title:   Competitive chlorination reactions in the gas phase: hydrogen and C1-C5 saturated hydrocarbons
Journal:   Trans. Faraday Soc.
Volume:   55
Page(s):  
Year:   1959
Reference type:   Journal article
Squib:   1959KNO/NEL937

Reaction:   C3H8 + ·Cl1-C3H7 + HCl
Reaction order:   2
Reference reaction:   C2H6 + ·Cl·C2H5 + HCl
Reference reaction order:   2
Temperature:   193 - 593 K
Pressure:  0.67 bar
Rate expression:   1.11±2.2x10-2 e166 [±41.57 J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
193 1.23E0
200 1.23E0
225 1.21E0
250 1.20E0
275 1.19E0
300 1.19E0
325 1.18E0
350 1.18E0
375 1.17E0
400 1.17E0
425 1.16E0
450 1.16E0
475 1.16E0
500 1.16E0
525 1.15E0
550 1.15E0
575 1.15E0
593 1.15E0