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Author(s):   Tschuikow-Roux, E.; Yano, T.; Niedzielski, J.
Title:   Reactions of ground state chlorine atoms with fluorinated methanes and ethanes
Journal:   J. Chem. Phys.
Volume:   82
Page(s):   65 - 74
Year:   1985
Reference type:   Journal article
Squib:   1985TSC/YAN65-74

Reaction:   C3H8 + ·Cl1-C3H7 + HCl
Reaction order:   2
Reference reaction:   CH4 + ·Cl·CH3 + HCl
Temperature:   281 - 368 K
Pressure:  2.67E-2 bar
Rate expression:   1.12x10-10 [±2.16x10-11 cm3/molecule s] e-1763 [±582 J/mole]/RT
Bath gas:   C3H8
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
281 5.27E-11
300 5.53E-11
325 5.84E-11
350 6.12E-11
368 6.30E-11