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Author(s):   DeMore, W.B.; Sander, S.P.; Golden, D.M.; Hampson, R.F.; Kurylo, M.J.; Howard, C.J.; Ravishankara, A.R.; Kolb, C.E.; Molina, M.J.
Title:   Chemical kinetics and photochemical data for use in stratospheric modeling. Evaluation number 12
Journal:   JPL Publication 97-4
Page(s):   1 - 266
Year:   1997
Reference type:   Journal article
Squib:   1997DEM/SAN1-266

Reaction:   Br· + NO2 → BrNO2
Reaction order:   3
Temperature:   200 - 300 K
Rate expression:   4.19x10-31 [±8.0x10-32 cm6/molecule2 s] (T/298 K)(-2.40±0.50)
Category:  Review
Data type:   Extensive literature review
Pressure dependence:   Rate constant is low pressure limit

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm6/molecule2 s]
200 1.09E-30
225 8.23E-31
250 6.39E-31
275 5.08E-31
300 4.12E-31