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Home ©NIST, 2013 Accessibility information |
Title: Thermal Decomposition of Branched Silanes: A Computational Study on Mechanisms
Journal: Chem. Euro. J.
Volume: 18
Page(s): 9106 - 9116
Year: 2012
Book Title: ''
Editor: ''
Publisher: ''
Publisher address: ''
Comments: ''
Reference type: Journal article
Squib: 2012EGE/GEN9106-9116
Reaction:
Si3H8 → SiH3SiH=SiH2 + H2
Reaction order:
1
Temperature:
298
K
Rate expression:
no rate data available
Category: Theory
Data type:
Ab initio
Pressure dependence:
None reported
Comments:
Reaction potential energy surface was studied using quantum chemistry. Room-temperature free energy of the transition state was calculated. No rate constant values were calculated.
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