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Author(s):   Eger, W.A.; Genest, A.; Rosch, N.
Title:   Thermal Decomposition of Branched Silanes: A Computational Study on Mechanisms
Journal:   Chem. Euro. J.
Volume:   18
Page(s):   9106 - 9116
Year:   2012
Book Title:   ''
Editor:   ''
Publisher:   ''
Publisher address:   ''
Comments:   ''
Reference type:   Journal article
Squib:   2012EGE/GEN9106-9116

Reaction:   Si3H8 → SiH3SiH=SiH2 + H2
Reaction order:   1
Temperature:   298 K
Rate expression:   no rate data available
Category:  Theory
Data type:   Ab initio
Pressure dependence:   None reported
Comments:   Reaction potential energy surface was studied using quantum chemistry. Room-temperature free energy of the transition state was calculated. No rate constant values were calculated.

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