Kinetics Database Resources
Rate Our Products and Services
Other Databases
NIST Standard Reference Data Program
NDRL-NIST Solution Kinetics Database
NIST Computational Chemistry Comparison and Benchmark Database
The NIST Reference on Constants, Units, and Uncertainty
Administrative Links
 |
Home ©NIST, 2013 Accessibility information |
Title: A reinvestigation of the kinetics and the mechanism of the CH3C(O)O-2+HO2 reaction using both experimental and theoretical approaches
Journal: Phys. Chem. Chem. Phys.
Volume: 8
Page(s): 2163 - 2171
Year: 2006
Reference type: Journal article
Squib: 2006LEC/RAY2163-2171
Reaction:
HO2 + CH3C(O)OO(·) → CH3C(O)OH + O3
Reaction order:
2
Reference reaction:
HO2 + CH3C(O)OO(·) → Products
Reference reaction order:
2
Temperature:
298
K
Pressure: 2.40E14 bar
Rate expression:
2.0x10-1±1.0x10-2
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Pressure dependence:
None reported
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Flash photolysis (laser or conventional)
Time resolution:
In real time
Analytical technique:
Vis-UV absorption
View full bibliographic record.