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Chemical Sciences Division
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Author(s):
Harding, L.B.; Klippenstein, S.J.; Georgievskii, Y.
Title:
On the combination reactions of hydrogen atoms with resonance-stabilized hydrocarbon radicals
Journal:
J. Phys. Chem. A
Volume:
111
Page(s):
3789 - 3801
Year:
2007
Reference type:
Journal article
Squib:
2007HAR/KLI3789-3801
Reaction:
Benzyl + H· → Products
Reaction order:
2
Temperature:
200 - 2000
K
Rate expression:
2.24x10-10 [cm3/molecule s] (T/298 K)0.22 e793 [J/mole]/RT
Category: Theory
Data type:
Transition state theory
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
| 200 |
3.30E-10 |
| 300 |
3.08E-10 |
| 400 |
3.04E-10 |
| 500 |
3.04E-10 |
| 600 |
3.07E-10 |
| 700 |
3.11E-10 |
| 800 |
3.15E-10 |
| 900 |
3.19E-10 |
| 1000 |
3.23E-10 |
| 1100 |
3.27E-10 |
| 1200 |
3.31E-10 |
| 1300 |
3.35E-10 |
| 1400 |
3.39E-10 |
| 1500 |
3.42E-10 |
| 1600 |
3.46E-10 |
| 1700 |
3.49E-10 |
| 1800 |
3.53E-10 |
| 1900 |
3.56E-10 |
| 2000 |
3.59E-10 |
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