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Title: 1127. Gas-phase eliminations. Part IV. The pyrolyses of isopropyl and s-butyl iodide
Journal: J. Chem. Soc.
Page(s): 5919 - 5929
Year: 1963
Reference type: Journal article
Squib: 1963HOL/MAC5919-5929
Reaction:
sec-C4H9I → CH3CH=CHCH3 + HI
Reaction order:
1
Temperature:
523 - 603
K
Pressure: 4.00E-3 - 0.12 bar
Rate expression:
1.58x1015 [s-1] e-200379 [±673 J/mole]/RT
Bath gas:
sec-C4H9I
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 523 | 1.54E-5 |
| 525 | 1.83E-5 |
| 550 | 1.47E-4 |
| 575 | 9.91E-4 |
| 600 | 5.68E-3 |
| 603 | 6.94E-3 |