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Accessibility information
Author(s):   Holmes, J.L.; Maccoll, A.
Title:   1127. Gas-phase eliminations. Part IV. The pyrolyses of isopropyl and s-butyl iodide
Journal:   J. Chem. Soc.
Page(s):   5919 - 5929
Year:   1963
Reference type:   Journal article
Squib:   1963HOL/MAC5919-5929

Reaction:   sec-C4H9ICH3CH=CHCH3 + HI
Reaction order:   1
Temperature:   523 - 603 K
Pressure:  4.00E-3 - 0.12 bar
Rate expression:   1.58x1015 [s-1] e-200379 [±673 J/mole]/RT
Bath gas:   sec-C4H9I
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
523 1.54E-5
525 1.83E-5
550 1.47E-4
575 9.91E-4
600 5.68E-3
603 6.94E-3