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Accessibility information
Author(s):   Nangia, P.S.; Benson, S.W.
Title:   Kinetics of the gas-phase addition of HI to butene-2
Journal:   J. Chem. Phys.
Volume:   41
Page(s):   530 - 537
Year:   1964
Reference type:   Journal article
Squib:   1964NAN/BEN530-537

Reaction:   sec-C4H9I → CH3CH=CHCH3 + HI
Reaction order:   2
Temperature:   565 - 607 K
Pressure:  0.12 - 0.20 bar
Rate expression:   7.42x10-11 [cm3/molecule s] e-157144 [J/mole]/RT
Bath gas:   HI
Category:  Theory
Data type:   Estimated: thermochemical, kinetic, or other

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
565 2.20E-25
575 3.94E-25
600 1.55E-24
607 2.23E-24