Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Feedback

Rate Our Products and Services

Help


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...


Administrative Links

NIST home page

MML home page

Chemical Sciences Division

  NIST Logo Home
©NIST, 2020
Accessibility information
Author(s):   Kaiser, E.W.; Wallington, T.J.; Hurley, M.D.
Title:   Kinetic study of the reaction of chlorine atoms with CF3I and the reactions of CF3 radicals with O2 and NO at 296 K
Journal:   Int. J. Chem. Kinet.
Volume:   27
Page(s):   205 - 218
Year:   1995
Reference type:   Journal article
Squib:   1995KAI/WAL205-218

Reaction:   CF3I + ·Cl·CF3 + ICl
Reaction order:   2
Reference reaction:   CH4 + ·Cl·CH3 + HCl
Reference reaction order:   2
Temperature:   271 - 363 K
Pressure:  0.48 bar
Rate expression:   6.5±4.6 e-1206 [±8314472 J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
271 3.81E0
275 3.84E0
300 4.01E0
325 4.16E0
350 4.30E0
363 4.36E0