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Author(s):   Manke, G.C., II; Setser, D.W.
Title:   Measuring gas-phase chlorine atom concentrations: rate constants for Cl + HN3, CF3I, and C2F5I
Journal:   J. Phys. Chem. A
Volume:   102
Page(s):   153 - 159
Year:   1998
Reference type:   Journal article
Squib:   1998MAN/SET153-159

Reaction:   CF3I + ·Cl·CF3 + ICl
Reaction order:   2
Temperature:   300 K
Pressure:  2.67E-3 bar
Rate expression:   5.1x10-13 [±1.48x10-13 cm3/molecule s]
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Electron beam
Time resolution:   In real time
Analytical technique:   Fourier transform (FTIR)

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