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Author(s):   Rao, V.S.; Takeda, K.; Skinner, G.B.
Title:   Formation of H and D atoms in pyrolysis of 1,3-butadiene and 1,3 butadiene-1,1,4,4,-d4 behind shock waves
Journal:   Int. J. Chem. Kinet.
Volume:   20
Year:   1988
Reference type:   Journal article
Squib:   1988RAO/TAK153

Reaction:   CD2=CHCH=CD2 → Products
Reaction order:   1
Temperature:   1520 - 2210 K
Pressure:  0.37 bar
Rate expression:   5.0x1011 [s-1] e-335073 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1520 1.53E0
1550 2.55E0
1600 5.76E0
1650 1.23E1
1700 2.53E1
1750 4.99E1
1800 9.45E1
1850 1.73E2
1900 3.07E2
1950 5.29E2
2000 8.87E2
2050 1.45E3
2100 2.32E3
2150 3.62E3
2200 5.54E3
2210 6.02E3