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Title: Formation of H and D atoms in pyrolysis of 1,3-butadiene and 1,3 butadiene-1,1,4,4,-d4 behind shock waves
Journal: Int. J. Chem. Kinet.
Volume: 20
Page(s):
Year: 1988
Reference type: Journal article
Squib: 1988RAO/TAK153
Reaction:
CD2=CHCH=CD2 → Products
Reaction order:
1
Temperature:
1520 - 2210
K
Pressure: 0.37 bar
Rate expression:
5.0x1011 [s-1] e-335073 [J/mole]/RT
Bath gas:
Ar
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Vis-UV absorption
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 1520 | 1.53E0 |
| 1550 | 2.55E0 |
| 1600 | 5.76E0 |
| 1650 | 1.23E1 |
| 1700 | 2.53E1 |
| 1750 | 4.99E1 |
| 1800 | 9.45E1 |
| 1850 | 1.73E2 |
| 1900 | 3.07E2 |
| 1950 | 5.29E2 |
| 2000 | 8.87E2 |
| 2050 | 1.45E3 |
| 2100 | 2.32E3 |
| 2150 | 3.62E3 |
| 2200 | 5.54E3 |
| 2210 | 6.02E3 |