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Author(s):   Enami, S.; Nakano, Y.; Hashimoto, S.; Kawasaki, M.; Aloisio, S.; Francisco, J.S.
Title:   Reactions of Cl atoms with dimethyl sulfide: A theoretical calculation and an experimental study with cavity ring-down spectroscopy
Journal:   J. Phys. Chem. A
Volume:   108
Page(s):   7785 - 7789
Year:   2004
Reference type:   Journal article
Squib:   2004ENA/NAK7785-7789

Reaction:   Adduct → (CH3)2S + ·Cl
Reaction order:   2
Temperature:   298 K
Pressure:  0.40 bar
Rate expression:   9.0x101 [±2.0x101 cm3/molecule s]
Category:  Theory
Data type:   Ab initio
Pressure dependence:   Rate constant is pressure dependent
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Vis-UV absorption
Comments:   Cavity Ringdown Spectroscopy. Ab initio calculation of equilibrium constant used with experimental data to obtain rate constant.

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