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Author(s):   Wallington, T.J.; Orlando, J.J.; Tyndall, G.S.
Title:   Atmospheric chemistry of chloroalkanes: intramolecular elimination of HCl from chloromethoxy radicals over the temperature range 264-336 K
Journal:   J. Phys. Chem.
Volume:   99
Page(s):   9437 - 9442
Year:   1995
Reference type:   Journal article
Squib:   1995WAL/ORL9437-9442

Reaction:   O2 + CH2ClO → HC(O)Cl + HO2
Reaction order:   2
Reference reaction:   CH2ClO → HCO + HCl
Reference reaction order:   1
Temperature:   264 - 336 K
Pressure:  0.93 bar
Rate expression:   5.6x10-23 [cm3/molecule] e27438 [±4939 J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Fourier transform (FTIR)

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule]
264 1.50E-17
275 9.11E-18
300 3.35E-18
325 1.44E-18
336 1.03E-18