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Title: Rates of addition of methyl radicals to olefins in the gas phase
Journal: J. Chem. Phys.
Volume: 46
Page(s):
Year: 1967
Reference type: Journal article
Squib: 1967CVE/IRW1694
Reaction:
(E)-2-C4H8 + ·CH3 → (CH3)2CHCH(·)CH3
Reaction order:
2
Reference reaction:
iso-C4H10 + ·CH3 → Other Products + CH4
Reference reaction order:
2
Temperature:
353 - 453
K
Pressure: 3.04 - 4.05 bar
Rate expression:
4.2 e-2054 [J/mole]/RT
Bath gas:
iso-C4H10
Category: Experiment
Data type:
Relative rate value measured
Excitation technique:
Direct photolysis
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [] |
|---|---|
| 353 | 2.09E0 |
| 375 | 2.17E0 |
| 400 | 2.27E0 |
| 425 | 2.35E0 |
| 450 | 2.43E0 |
| 453 | 2.43E0 |